Bio‐based Ester Oils for Use as Lubricants in Metal Working     

Hubertus Wichmann  Muefit Bahadir 《洁净——土壤、空气、水》2007,35(1):49-51

The potential application of bio‐based ester oils for use as lubricants in metal working has been investigated for sustainable production processes in the future. When waste edible and animal fats came into focus as starting materials, it was already proven, that ester oils produced from plant fats performed very well as cooling lubricants. Waste fats were first characterized by analyzing and monitoring samples for one complete year. Inorganic and organic contaminations were found to be low and without seasonal variations. Fatty acid methyl esters (FAME) were produced by transesterification of the waste fats and they were separated into fractions with saturated FAME or unsaturated FAME by fractional crystallisation (winterisation). Further transesterification with 2‐ethylhexanol led to products that could be successfully tested as lubricants. The development of an extraction process aimed at the recycling of oil containing grinding mud by enabling the recirculation of lubricating oil and reutilization of oil‐free metal chips.  相似文献   

盐湖相低熟油脂肪酸的组成与分布特征   总被引：7，自引：4，他引：3  

张松林  崔明中  李振西  王有孝  范璞 《沉积学报》1999,17(1):130-155

对泌阳凹陷碱性盐湖相、舞阳凹陷盐湖相、襄城凹陷膏盐湖相、南阳凹陷淡水湖相低熟油脂肪酸组成和分布特征进行了分析与研究。结果表明这些不同盐湖相的低熟原油的脂肪酸为丰度不同的饱和正构酸、不饱和正构酸、少量异构酸、类异戊二烯酸及脂肪酸乙酯系列化合物。脂肪酸的组成和分布反映了原始有机质的来源。  相似文献   

Exposure of amino acids and derivatives in the Earth orbit     

Bernard Barbier  Odile HeninFrançois Boillot  Annie ChabinDidier Chaput  André Brack 《Planetary and Space Science》2002,50(4):353-359

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Seasonality in UV transparency of an alpine lake is associated to changes in phytoplankton biomass   总被引：1，自引：0，他引：1  

Ruben Sommaruga  Günther Augustin 《Aquatic Sciences - Research Across Boundaries》2006,68(2):129-141

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初论塔里木盆地砂岩储层中SiO₂的溶蚀类型及其机理   总被引：8，自引：2，他引：8       下载免费PDF全文

钟大康  朱筱敏  周新源  王招明 《地质科学》2007,42(2):403-414

根据显微镜观察,塔里木盆地砂岩储层中SiO₂溶蚀分为石英颗粒边缘溶蚀、次生加大边溶蚀和交代溶蚀。通过对石英颗粒和加大边溶蚀特征及其与粘土矿物组合、与碳酸盐胶结、与古油藏破坏以及现今油田水中Si离子含量等关系的综合研究,这些SiO₂溶蚀可能存在两种机理:碱性环境下的SiO₂溶蚀和有机酸(烃类微生物降解产生的有机酸以及有机质成熟产生的有机酸)引起的SiO₂溶蚀。第一种溶蚀类型较普遍,但程度微弱;第二种溶蚀类型主要发生在古油藏破坏和有机质成熟过程中,这种溶蚀较强烈但很局限。SiO₂的溶蚀作用可以为油气提供一定量的储集空间,这对于深埋的时代较老的志留-泥盆系储层具有重要意义。在古油藏中尽管烃类已经充注储层孔隙,但只要孔隙中存在有机酸或碱性孔隙水,SiO₂的溶蚀和石英次生加大的胶结等作用仍可进行。  相似文献   

Evaluation ofCitrullus colocynthis, a desert plant native in Israel, as a potential source of edible oil     

Dan Schafferman  Alex Beharav  Ella Shabelsky  Zohara Yaniv 《Journal of Arid Environments》1998,40(4):431-439

Citrulus colocynthis(wild gourd) is a desert plant of the Cucurbitaceae, naturally adapted to arid environments. It was known in biblical times as a source of seed oil and its fruits were used as an efficient laxative. Accessions were collected in Israel and evaluated as a potential oil seed crop adapted to arid zones. It was found that its oil composition is similar to safflower oil, with a total of 80-85% unsaturated fatty acids. A potential yield of oil of 250-400 l ha⁻¹was calculated. The best yield was obtained during the first 4 weeks of the 10-week maturation period. Yield potential should be estimated under desert conditions in order to evaluate the plant's economic future as a crop suitable for an arid environment.  相似文献   

Thymol as a Biocide in Japanese Rainwater     

G. P. Ayers  N. Fukuzaki  R. W. Gillett  P. W. Selleck  J. C. Powell  H. Hara 《Journal of Atmospheric Chemistry》1998,30(2):301-310

Rainwater samples (wet-only; event samples) collected in Niigata in late autumn 1996 and springtime 1997 were used to assess the effectiveness of thymol as a biocide in Japanese rainwater. Upon collection each rainwater sample was divided into sub-samples, with thymol added to one sub-sample. Sub-samples with and without thymol were shipped to CSIRO, Australia, for chemical analysis. Comparison of analytical results for each pair of sub-samples proved the effectiveness of thymol in preventing biological action in this region where effects of rainwater microflaura and fauna on rainwater composition have not before been studied. Sub-samples without thymol exhibited lowered electrical conductivity, loss of the cations H⁺ and NH ₄ ^- , and loss of the anions HCOO^-, CH₃COO^-, C₂O ₄ ^2- , CH₃SO ₃ ^- and PO ₄ ^3- . Nitrate showed no change in all but one of the samples, indicating that ammonia was the preferred source of nitrogen for the biological processes that consumed the rainwater organic acids and phosphate. These results suggest that thymol is a suitable rainwater biocide for use under Japanese conditions.  相似文献   

Soldier crab (Dotilla myctiroides) distribution,food resources and subsequent role in organic matter fate in Ao Tang Khen,Phuket, Thailand     

Kimberly K. Takagi  Phaothep Cherdsukjai  Izumi Mimura  Yuka Yano  Kanjana Adulyanukosol  Makoto Tsuchiya 《Estuarine, Coastal and Shelf Science》2010

This study aimed to elucidate Dotilla myctiroides (H. Milne-Edwards) food resources and how the soldier crab influences the organic matter composition on the intertidal flat. A preliminary assessment of D. myctiroides size, sex, and population distribution was conducted to clarify the characteristics of the inhabiting population. Overall, D. myctiroides size and abundance was normal across the tidal flat area. Comparison of different sediment types from the soldier crab habitat (surface sediments, igloos, burrow lining, burrow pellets, feeding pellets, and feces) using the fatty acid (FA) analysis technique revealed D. myctiroides removes organic matter via the significantly lower contributions of polyunsaturated FAs, essential FAs, and dinoflagellates in the feeding pellets. Dotilla myctiroides tissue analysis of the hepatopancreas and hindgut in individuals that had been starved for 24 h confirmed not only the consumption of dinoflagellates, but diatoms and macroalgae as well. In addition, the FA metabolism within the digestive system implied the ability of the soldier crab to synthesize highly unsaturated FAs (HUFAs) such as 20:4n–6, 20:5n–3 and 22:6n–3.  相似文献   

冷冻牡蛎贮存过程中脂溶性有毒物质的变化研究     

张宁  林洪  隋涛  钟响  张艺兵  刘峰 《中国海洋大学学报(自然科学版)》2010,40(1)

牡蛎是我国出口量较大的水产品之一,由于产品本身的特殊性,在生长过程中易产生腹泻性贝毒(DSP).本实验中原料牡蛎DSP生物法检测结果为阴性,冷冻贮存4个月后检测结果即为阳性.本研究以分析这一变化原因为目的,采用LC-MS法对DSP生物检测的阳性样品进行确认,结果表明,生物法DSP检测的结果为假阳性,造成生物法DSP检测中小白鼠死亡的是牡蛎在贮藏过程中产生的脂溶性有毒物质.进一步分析确定该有毒物质为牡蛎脂肪水解物--游离脂肪酸.同时本研究对牡蛎在不同贮存温度和贮存时间下产生的游离脂肪酸含量进行了测定,在-10 ℃贮存温度下,贮存0,2,4,6,8,10个月,游离脂肪酸的变化范围为5.2～788.6 mg/kg;在-10 ℃,-18 ℃,-25 ℃贮存温度下,贮存4个月,游离脂肪酸的变化范围为92.5～389 mg/kg.  相似文献   

高体革鯻幼鱼肌肉营养成分分析     

马国红  刘羽清  师吉华  张延华  王爱英  卢红 《广东海洋大学学报》2009,29(1)

检测了高体革鯻(Scortum bacoo)幼鱼肌肉营养组成,结果表明:高体革鯻粗蛋白质量分数为17.77%,粗脂肪质量分数为3.42%,水解氨基酸总质量分数为15.71%,其中必需氨基酸质量分数为7.50%,占氨基酸总量的47.74%,鲜味氨基酸总质量分数为5.46%,占氨基酸总量的34.75%,必需氨基酸指数为88.60。说明高体革鯻具有较高的营养价值和养殖价值。  相似文献